arXiv:2307.11372math.PR
On the origin of the Boltzmann distribution
Abstract
The family of Boltzmann distributions is used in statistical mechanics to describe the distribution of states in systems with a given temperature. We give a novel characterization of this family as the unique one satisfying independence for uncoupled systems. The theorem boils down to a statement about endomorphisms of the convolution semi-group of finitely supported probability measures on the natural numbers, or, alternatively, about endomorphisms of the multiplicative semi-group of polynomials with non-negative coefficients.
More specifically, dice-inspired (positive integer-related) probability distributions https://arxiv.org/abs/2307.11372 tilt maps [on dice polynomials].. that are measure-class-preserving and commute with convolution. as an alternative to max entropy to derive Boltzmann law for…
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